Vol. 337 No. 10 (2026)
DOI https://doi.org/10.18799/24131830/2026/10/5373
Ecological assessment of tailings dumps substrates and soils pollution with main ore (Zn, Pb, Cd) and mineralization-associated (Cd) metals in the North-West Altai mining landscapes technogenic impact zone
Relevance. The need for continuous monitoring of abandoned and dried-out tailings dumps as sources of environmental pollution, understanding the mechanisms of toxicant migration as a result of erosion and deflation processes on the tailings dumps, and identifying the role of reclamation measures in reducing the negative impact on the environment. Aim. To investigate the concentrations of priority heavy metals in the upper layers of tailings substrates of the Altai Mining and Processing Plant and in the soils of its vicinity, and to provide the integral ecological assessment of their contamination. Methods. Determinations of heavy metals in soils upper layers are carried out by the method of atomic absorption spectrometry on a Quantum-2mt device, with preliminary sequential samples treatment with acids (HCl, HNO3, HF, H2SO4). The data were processed using statistical methods. Individual and integrated indexes of soil and ground metal contamination were calculated. Results and conclusions. It is established that concentrations of primary ore metals (Zn, Cu, Pb) and mineralization-associated metals (Cd) in the substrates of the Altai Mining and Processing Plant tailing dumps significantly exceed both the estimated permissible concentrations and the background levels in the chernozems of North-Western Altai. The upper layers of the old and new tailing dumps differ significantly in their saturation with heavy metals. Thus, the soil-like ground of the new tailing dump reclaimed areas sown with forbs contains on average 250±41 mg/kg of zinc, 98±17 mg/kg of copper and 102±15 mg/kg of lead, whereas in the substrate of the perimeter of the old tailing dump under single plant specimens, the metal content is noticeably higher, on average 444±76 (up to 642) mg/kg of Zn, 332±68 (up to 1516) mg/kg of Cu and 175±26 (in some cases up to 1828) mg/kg of Pb. Zinc, with low PI and Igeo, poses the least threat to the soil cover of the study area. The upper horizons of meadow soils in landscapes geochemically subordinated to tailings dumps, containing material washed from the eroded sides of tailings dumps, are characterized by the highest concentrations of Cu and Pb. These soils exhibit the highest degree of integrated soil contamination according to the Nemerov index (NPI=22), as well as extremely hazardous (Zc=165) and high (Zc=79) values of total metal contamination. The highest Zn and Cd contents were found in the substrate on the surface of the new tailing dump near the illegal municipal waste dump. The dispersion of Altai Mining and Processing Plant tailing dump and the airborne migration of toxic dust extend up to 2 km (in the direction of prevailing winds), which is confirmed by the contamination of the upper soil layers of adjacent natural ecosystems with copper, zinc, lead, and cadmium. At a distance of 3 km from the Altai Mining and Processing Plant tailing dumps, soil contamination with heavy metals is no longer detectable.
For citation: Baboshkina S.V., Puzanov A.V., Balykin S.N., Saltykov A.V., Rozhdestvenskaya T.A., Troshkova I.A. Ecological assessment of tailings dumps substrates and soils pollution with main ore (Zn, Pb, Cd) and mineralization-associated (Cd) metals in the North-West Altai mining landscapes technogenic impact zone. Bulletin of the Tomsk Polytechnic University. Geo Assets Engineering, 2026, vol. 337, no. 10, pp. 159–171. http://doi.org/10.18799/24131830/2026/10/5373
Keywords:
Altai Mining and Processing Plant, zinc, copper, lead, cadmium, tailings dumps, soil pollution indexes, reclamation
References:
1. Mouhsine E., Ouazzani N., Gharmali A., Berrekhis F., Valiente M., Mandi L. Speciation of heavy metals in the soil and the tailings, in the zinc-lead Sidi Bou Othmane Abandoned Mine. Environmental Earth Sciences, 2013, vol. 3 (8), pp. 138–146.
2. Sarapulova G.I. Geochemical assessment of the “surface water–bottom sediments” system in the zone of mining industrial technogenesis. Sustainable Development of Mountain Territories, 2024, no. 16, pp. 83–93. (In Russ.) DOI: 10.21177/1998-4502-2024-16-1-83-93
3. Mesyats S.P., Volkova E.Yu. Modern remediation concept for mining industrial rock dumps view. Mining information and analytical bulletin, 2015, vol. 56, pp. 467–478. (In Russ.)
4. Blowes D.W., Ptacek C.J., Jambor J.L., Weisener C.G. The geochemistry of acid mine drainage. Treatise on Geochemistry. Eds. K. Turekian, H. Holland. Oxford, Elsevier Science, 2003. Vol. 9. pp. 149–204.
5. Wu P., Chen B., Li R., Li R. Prediction of heavy metal ion distribution and Pb and Zn ion concentrations in the tailing pond area. PLOS ONE, 2024, vol. 19, pp. 1–18. DOI: 10.1371/journal.pone.0308916
6. Kabata-Pendias A. Trace elements in soils and plants. 4th ed. Boca Raton, CRS Press, 2011. 548 р.
7. Rikhvanov L.P., Ambrosimova N.A., Baranivskaya N.V., Belan L.N. Biogeochemical monitoring in the areas of tailings storage facilities of mining enterprises taking into account microbiological factors of transformation of mineral components. Novosibirsk, Siberian Branch of the Russian Academy of Sciences Publ. house, 2017. 437 p. (In Russ.)
8. Varol M. Assessment of heavy metal contamination in sediments of the Tigris River (Turkey) using pollution indices and multivariate statistical techniques. Journal of Hazardous Materials, 2011, vol. 195, pp. 355–364.
9. Min X., Xie X., Chai L., Liang Y., Li M., Ke Y. Environmental availability and ecological risk assessment of heavy metals in zinc leaching residue. Transactions of Nonferrous Metals Society of China, 2013, vol. 23 (1), pp. 208–218. DOI: 10.1016/S1003-6326(13)62448-6.
10. Khrapai E.S., Kuzina A.A., Kolesnikov S.I., Minnikova T.V., Kazeev K.Sh. Heavy metal content of soils at tailings pond after reclamation at Urup Mining and Processing Plant. Mining Informational and Analytical Bulletin, 2024, no. 4, pp. 56–68. (In Russ.)
11. MU 2.1.7.730-99 2.1.7. Methodical instructions. Soil, cleaning of populated areas, household and industrial waste, sanitary protection of soil. Hygienic assessment of soil quality in populated areas. Moscow, Federal Center for State Sanitary and Epidemiological Surveillance of the Ministry of Health of Russia Publ., 1999. 18 p. (In Russ.)
12. Kowalska J., Mazurek R., Gąsiorek M., Zaleski T. Pollution indices as useful tools for the comprehensive evaluation of the degree of soil contamination: a review. Environmental Geochemistry and Health, 2018, vol. 40, pp. 2395–2420.
13. Müller G. Heavy metals in the sediments of the Rhine: changes since 1971. Umschau in Wissenschaft und Technik, 1979, vol. 79, pp. 778–783. (In Germ.)
14. Nowrouzi M., Pourkhabbaz A. Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Hara Biosphere Reserve, Iran. Chemical Speciation & Bioavailability, 2014, vol. 26. pp. 99–105.
15. Avdoshchenko V.G., Klimova A.V. Assessment of heavy metal pollution in the soils of Petropavlovsk-Kamchatsky, Kamchatka territory. Bulletin of Kamchatka state technical university, 2022, vol. 61, pp. 65–81. DOI: 10.17217/2079-0333-2022-61-65-81
16. Gong Q., Deng J., Yunchuan X., Qingfei W., Ya L. Calculating pollution indices by heavy metals in ecological geochemistry assessment and a case study in parks of Beijing. Journal of China University of Geosciences, 2008, vol. 19 pp. 230–241. DOI: 10.1016/S1002-0705(08) 60042-4
17. Madalina-Flavia I., Radu S. Assessment of the pollution level and determination of the geo-accumulation index of heavy metals in the soil from the old funicular dump area – uricani. Mining Revue, 2024, vol. 30, pp. 98–105. DOI: 10.2478/minrv-2024-0046
18. Hu B., Jia X., Hu J., Xu D., Xia F., Li Y. Assessment of heavy metal pollution and health risks in the soil-plant-human system in the Yangtze River Delta, China. International Journal of Environmental Research and Public Health, 2017, vol. 14, pp. 1042–1051. DOI: 10.3390/ijerph14091042
19. Opekunova M.G., Opekunov A.Y., Kukushkin S.Y., Lisenkov S.A., Vlasov S.V., Somov V.V. Soil pollution with polycyclic aromatic hydrocarbons and petroleum hydrocarbons in the North of Western Siberia: spatial pattern and ecological risk assessment. Eurasian Soil Science, 2022, vol. 55 (11), pp. 1647–1664 DOI: 10.1134/S1064229322110102
20. GN 2.1.7.2511–09 Hygienic standards. Approximately permissible concentrations (APC) of chemical substances in soil. Moscow, Federal Center for Hygiene and Epidemiology of Rospotrebnadzor Publ., 2009. 11 p. (In Russ.)
21. Sayet Y.E., Revich B.A., Yanin E.P. Environmental geochemistry. Moscow, Nedra Publ., 1990. 335 p. (In Russ.)
22. Guo M., Xiao Y., Zhang J., Wei L., Wei W., Xiao L., Fan R., Zhang T., Zhang G. Insights into the pattern of the persistent heavy metal pollution in soil from a six-decade historical small-scale Lead-Zinc Mine in Guangxi, China. Processes, 2024, vol. 12 (8) pp. 1745–1751. DOI: 10.3390/pr12081745.
23. Puzanov A.V., Baboshkina S.V., Gorbachev I.V. Characteristics of heavy metal migration in the natural-anthropogenic anomalies of the North-Western Аltai. Geochemistry International, 2012, vol. 50 (4), pp. 358–366.
24. Ivanov V.V. Ecological geochemistry of the elements. A reference book in six volumes. Edited by E.K. Burenkov. Moscow, Nedra Publ., 1996.
25. Guo W., Zhao R-X., Zhang J., Bao Y-Y., Wang H., Yang M., Sun X., Jin F. Distribution characteristic and assessment of soil heavy metal pollution in the iron mining of Baotou in Inner Mongolia. Huan jing ke xue, 2011, vol. 32 (10) pp. 3099–3105.


