Vol. 337 No. 3 (2026)
DOI https://doi.org/10.18799/24131830/2026/3/5200
Boron acid recovery from the separate of geothermal heat carrier of the Pauzhetskaya GeoPP
Geothermal energy is one of the modern renewable sources of electrical energy. Geothermal heat carriers are considered not only as sources of electrical and thermal energy, but also as sources of chemical compounds. In developing and operating geothermal power plants, great attention should be paid to the ecology of the surrounding areas. The exploitation of geothermal plants results in the formation of wastewater, which is fully or partially discharged into the territories adjacent to the geothermal field, as well as into water bodies. In particular, such contaminants are boron compounds, the concentration of which in geothermal waters has a wide range from less than 10 to more than 500 mg/l in terms of boric acid. Relevance. The recovery of chemical compounds from geothermal heat carriers along with the generation of electricity allows for the complex utilisation of mineral natural resources. Aim. To review the methods of recovery of boron compounds from hydro-mineral raw materials in recent years and to update the data on the composition of the Pauzhetskaya GeoPP geothermal heat carrier separate. Results and conclusions. In the process of discharging the Pauzhetskaya GeoPP geothermal heat carrier separate, the Bystry brook and the Pauzhetka river are exposed to boron compounds pollution. The Pauzhetskaya GeoPP separate contains up to 200 mg/l of boric acid. In order to prevent technogenic impact on water bodies of fishery importance, it is necessary to process the separate in order to adjust the content of regulated components to the level of maximum allowable concentrations. The most widespread methods of boron-containing solutions processing are electrochemical and sorption methods using ion-exchange resins, membranes and boron-selective sorbents. The most common inorganic sorbents are natural and modified zeolite of the Yagodninskoe deposit of the Kamchatka region, cryo-granulated zirconium hydroxide and modified pumice.
For citation: Avfukova L.S., Belova T.P. Boron acid recovery from the separate of geothermal heat carrier of the Pauzhetskaya GeoPP. Bulletin of the Tomsk Polytechnic University. Geo Assest Engineering, 2026, vol. 337, no. 3, pp. 74–84. https://doi.org/10.18799/24131830/2026/3/5200
Keywords:
geothermal field, geothermal heat carriers, sorption, sorption capacity, ion-exchange resins, boron, boric acid
References:
1. ORDER of December 13, 2016 N 552. Order of the Ministry of Agriculture of the Russian Federation «on approval of water quality standards for water bodies of fishery importance, including standards for maximum permissible concentrations of harmful substances in the waters of water bodies of fishery importance» with changes as of June 13, 2024. Moscow, 2024. 104 p. (In Russ.)
2. Maksin V.I., Akhmedov M.I., Ramazanov A.Sh. Coprecipitation of boron with magnesium hydroxide from highly mineralized thermal waters. Chemistry and technology of water, 1990, vol. 12, no. 1, pp. 11–14. (In Russ.)
3. Pakholkov V.V., Shuvalov R.A. Pollution of surface waters with boric acid during exploitation of geothermal deposits. Abstracts of reports of the scientific and practical conference on nature conservation and rational use of natural resources of Kamchatka. Petropavlovsk-Kamchatsky, 1979. pp. 91–93. (In Russ.)
4. Belova T.P., Ershova L.S. Boron concentration by industrial anion exchanger resins from model solutions in a dynamic mode. Heliyon, 2021, vol. 7, Iss. 2, 7 p. DOI: 10.1016/j.heliyon.2021.e06141.
5. Belova T.P., Parshin B.E., Latkin A.S., Yakovishina O.A., Zernova L.D., Kornilova T.I., Ratchina T.I. Study of sorption extraction of boron from the geothermal heat carriers. Proceedings, Thirty-Fourth Workshop on Geothermal Reservoir Engineering Stanford University. Stanford, California, February 9–11, 2009. pp. 408.
6. Belova T.P. Experimental studies of sorption extraction of boron and lithium from thermal waters. Volcanology and Seismology, 2017, no. 2, pp. 38–44. (In Russ.) DOI: 10.7868/S020303061702002X.
7. Ershova L.S., Belova T.P. Research of boron sorption by industrial anion exchangers from model solutions of simulating geothermal heat carriers in dynamic mode. Bashkir Chemical Journal, 2019, vol. 26, no. 4, pp. 74–77. (In Russ.) DOI: 10.17122/bcj-2019-4-74-77.
8. Lipunov I.N., Pervova I.G., Nikiforov A.F., Klepalova I.A. Dynamics of boric acid sorption by boron-selective SB-type anionite. Water management of Russia: problems, technologies, management, 2021, no. 5, pp. 112–124. (In Russ.) DOI: 10.35567/1999-4508-2021-5-8.
9. Lipunov I.N., Pervova I.G., Nikiforov A.F. Sorption of boric acid using polycondensation anion exchangers. News of universities. Chemistry and chemical technology, 2021, vol. 64, Iss. 8, pp. 42–48. (In Russ.) DOI: 10.6060/ivkkt.20216408.6320.
10. Ramazanov A.Sh., Kasparova M.A., Kunzhueva K.G. On the prospect of extraction of boron compounds in the complex processing of geothermal brines. Bulletin of Dagestan State University Series 1. Natural Sciences, 2022, vol. 37, Iss. 4, pp. 84–93. (In Russ.) DOI: 10.21779/2542-0321-2022-37-4-84–93.
11. Zhuravlev V.I. Study of sorption purification of lithium hydroxide solutions from aluminum by resin ANB-11g. News of higher educational institutions. Non-ferrous metallurgy, 2011, no. 6, pp. 21–25. (In Russ.)
12. Figueira M., Reig M., Fernández de Labastida M., Cortina J.L., Valderrama C. Boron recovery from desalination seawater brines by selective ion exchange resins. Journal of Environmental Management, 2022, vol. 314, pp. 114984. DOI: 10.1016/j.jenvman.2022.114984.
13. Taşçı T., Hepyalçın S., Ciğeroğlu Z., Küçükyıldız G., Şahin S., Vasseghian Y. Boron removal from aqueous solutions by chitosan/functionalized-swcnt-cooh: development of optimization study using response surface methodology and simulated annealing. Chemosphere, 2022, vol. 288, pp. 132554. DOI: 10.1016/j.chemosphere.2021.132554.
14. Al-dhawihamsul B.N.S., Kutty R.M., Hayder G., Elamin B. Adsorptive removal of boron by DIAION™ CRB05: characterization, kinetics, isotherm, and optimization by response surface methodology. Processes, 2023, vol. 11, no. 2, pp. 453. DOI: 10.3390/pr11020453.
15. Koseoglu P., Yoshizuka K., Nishihama S., Yuksel U., Kabay N. Removal of boron and arsenic from geothermal water in Kyushu Island, Japan, by using selective ion exchange resins. Solvent Extraction and Ion Exchange, 2011, vol. 29, no. 3, pp. 440–457. DOI: 10.1080/07366299.2011.573448.
16. Korkmaz M., Özmetin C., Özmetin E., Süzen Y. Modelling of boron removal from solutions by ion exchange for column reactor design in boron mine wastewater treatment. Desalination and Water Treatment, 2020, vol. 179, pp. 63–74. DOI: 10.5004/dwt.2020.25041.
17. Lee C.-H., Chen P.-H., Chen W.-S. Recovery of boron from desalination brine through Amberlite IRA 743 resin. Desalination and Water Treatment, 2022, vol. 264, pp. 133–140. DOI: 10.5004/dwt.2022.28569.
18. Baba A., Recepo˘glu Y.K., Uzelli T., Gören A.Y. Boron in geothermal energy: Sources, environmental impacts, and management in geothermal fluid. Renewable and Sustainable Energy Reviews, 2022, vol. 167, no. 1, pp. 15. DOI: 10.1016/j.rser.2022.112825.
19. Butskikh E.A., Voronyuk I.V., Eliseeva T.V., Polikarpov A.P., Shunkevich A.A. Sorption of boric acid by FIBAN anion-exchange fibers. Protection of Metals and Physical Chemistry of Surfaces, 2023, vol. 59, no. 2, pp. 117–122. DOI: 10.1134/S2070205123700156.
20. ¨Ocal Z.B., ¨Oncel M.S., Keskinler B., Khataee A., Karagündüz A. Sustainable treatment of boron industry wastewater with precipitation-adsorption hybrid process and recovery of boron species. Process Safety and Environmental Protection, 2023, vol. 182, pp. 719–726. DOI: 10.1016/j.psep.2023.12.006.
21. Song T., Gao F., Du X., Hao X.-G., Liu Z. Removal of boron in aqueous solution by magnesium oxide with the hydration process. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, vol. 665, pp. 131211. DOI: 10.1016/j.colsurfa.2023.131211.
22. Goren A.Y., Recepoglu Y.K., Karagunduz A., Khataee A. A review of boron removal from aqueous solution using carbon-based materials: an assessment of health risks. Chemosphere, 2022, vol. 293, no. 4, pp. 133587. DOI: 10.1016/j.chemosphere.2022.133587.
23. Gómez D.N., Legua P., Lidón V., Conesa A., Nicolás J.J.M., Melgarejo P. Evaluation of agricultural soil-improving zeolite for improving irrigation water quality. Applied Sciences (Switzerland), 2024, vol. 14, no. 1, pp. 418. DOI: 10.3390/app14010418.
24. Tanasheva M.R., Beisembaeva L.K., Sydykbayeva S.A., Shenebekova G.S. Non-organic sorbent of industrial wastes for the borium allocation from natural waters. Bulletin of al-Farabi Kazakh national university. The chemical series, 2011, no. 1 (61), pp. 148–152. (In Russ.)
25. Yetgin A.G., Dündar O.A., Çakmakçı E., Arar ¨O. Removal of boron from aqueous solution by modified cellulose. Biomass Conversion Biorefinery, 2022, vol. 13, no. 14, pp. 13081–13090. DOI: 10.1007/s13399-021-02133-1.
26. Qurbonov A.S., Davlatov A.S., Sumani N., Akramzoda R.D., Boboev K.O. Extraction of boric acid from brine of Sasykkul lake, Tajikistan with monoatic aliphatic alcohols. Bulletin of Bokhtar State University named after Nosiri Khusrav. Natural Sciences Series, 2023, no. 2–3 (113), pp. 83–86.
27. Xu Z., Su H., Zhang J., Liu W., Zhu Z., Wang J., Chene J., Qi T. Recovery of boron from brines with high magnesium content by solvent extraction using aliphatic alcohol. Royal Society of Chemistry, 2021, vol. 11, pp. 16096–16105. DOI: 10.1039/D1RA01906F.
28. Khoroshilov A.V., Ivanov P.I. Investigation of the process of boric acid extraction by tributyl phosphate. Advances in Chemistry and Chemical Technology, 2015, vol. 29, no. 6, pp. 59–61. (In Russ.)
29. Akramzoda R.J., Kurbonov A.S., Tagoev M.M., Mirsaidov U.M. Boric acid extraction from the brine of lake Sasyk-Kul Tajikistan with isobutyl alcohol and tributyl phosphate. Reports of National Academy of Sciences of Tajikistan, 2021, vol. 64, no. 9–10, pp. 542–546.
30. Lanina T.D., Bykov I.Yu. Extraction of boron from formation waters. Construction of oil and gas wells on land and sea, 2008, no. 10, pp. 24–32. (In Russ.)
31. Shulyupin A.N., Chemev I.I. The problems and prospects of Kamchatka geothermal resource development. Georesources, 2012, no. 1 (43), pp. 19–21. (In Russ.)
32. Mehanathan S., Jaafar J., Nasir A.M., Rahman R.A., Ismail A.F., Illias R.M., Othman M.H.D., Rahman M.A, Bilad M.R., Naseer M.N. Adsorptive membrane for boron removal: challenges and future prospects. Membranes, 2022, vol. 12, pp. 798. DOI: 10.3390/membranes12080798.
33. Lokarev A.V., Potapov V.V., Kanarsky A.V. Concentration of salts of hydrothermal waters by reverse osmosis. Bulletin of the Technological University, 2017, vol. 20, no. 18, pp. 78–80. (In Russ.)
34. Li X., Wang Z., Han X., Wang J. Facile fabrication of hydroxyl-rich polyamide TFC RO membranes for enhanced boron removal performance. Desalination, 2022, vol. 531, pp. 115723. DOI: 10.1016/j.desal.2022.115723.
35. Mutlu Salmanli O., Yuksekdag A., Koyuncu I. Boron removal by using vacuum assisted air gap membrane distillation (VAGMD). Environmental Technology and Innovation, 2022, vol. 26, pp. 102395. DOI: 10.1016/j.eti.2022.102395.
36. Hung W., Horng R.S., Tsai C. Effects of process conditions on simultaneous removal and recovery of boron from boron-laden wastewater using improved bipolar membrane electrodialysis (BMED). Journal of Water Process Engineering, 2022, vol. 47, pp. 102650. DOI: 10.1016/j.jwpe.2022.102650.
37. Antipov M.A., Medvedev M.S., Klimenko I.A., Krupoderov V.S. Development of sorption technology for processing thermal waters of the Pauzhetka steam-hydrothermal field. Abstracts of the International Conference. Extraction of Mineral Components from Geothermal Solutions. Petropavlovsk-Kamchatsky, September 12–15, 2005. Petropavlovsk-Kamchatsky, OTTISK Publ., 2005. pp. 36–38. (In Russ.)
38. Pashkevich R.I., Veselko A.U., Popov G.V. Chemical composition of heater of Payzhetsk geothermal field. Mining Informational and Analytical Bulletin (scientific and technical journal), 2016, no. S40, pp. 183–190. (In Russ.)
39. Veselko A.Yu., Popov G.V. By the impact of the flue coolant Pauzhetskaya and Paratunskaya geothermal field in watercourses. Mining Informational and Analytical Bulletin, 2017, no. 12 (special issue 35), pp. 125–129. (In Russ.) DOI: 10.25018/0236-1493-2017-12-35-125-129.
40. Gorbach V.A. Waste disposal coolant during operation of geothermal fields in Kamchatka. Mining Informational and Analytical Bulletin (scientific and technical journal), 2016, no. S31, pp. 478–486. (In Russ.)
41. Nesterov D.V. Synthesis of new boron-chelating ligands – derivatives of 3-aminopropanediol-1, 2. Cand. Diss. Abstract. Yekaterinburg, 2018. 143 p. (In Russ.)
42. Rodionov A.I., Voitova O.M., Romanov N.Ya. Current state of the problem of wastewater purification from boron. Russian Chemical Reviews, 1991, vol. 60, Iss. 11, pp. 1271–1279. (In Russ.) DOI: 10.1070/RC1991v060n11ABEH001144.
43. Belova T.P., Ershova L.S. Sulfate and chloride-ions influence on boric acid sorption from separate of Pauzhetskaya geothermal station by modified zeolite. Mining Informational and Analytical Bulletin (scientific and technical journal), 2018, no. S57, pp. 354–360. (In Russ.) DOI: 10.25018/0236-1493-2018-12-57-354-360.
44. Butuzov V.A. History and development problems of geothermal power industry in Russia. Journal of Environmental Earth and Energy Study, 2019, no. 4 (4), pp. 4–19. (In Russ.) DOI: 10.5281/zenodo.3662719.


